Colloid Mobilization and Transport in Undisturbed Soil Columns. II. The Role of Colloid Dispersibility and Preferential Flow
Charlotte Kjaergaard*,a,c,
Per Moldrupa,
Lis W. de Jongeb and
Ole H. Jacobsenb
a Environmental Engineering Section, Dep. of Life Sciences, Aalborg University, Sohngaardsholmsvej 57, DK-9000 Aalborg, Denmark
b Dep. of Agroecology, Danish Institute of Agricultural Sciences, P.O. Box 50, DK-8830 Tjele, Denmark
c Currently Danish Institute of Agricultural Sciences, Department of Agroecology, P.O. Box 50, DK-8830 Tjele, Denmark

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Fig. 1. Conceptualization of the processes involved in colloid mobilization in structured soils (a) the diffusive displacement of highionic strength intraaggregate water with lowionic strength infiltration water, (b) the actual dispersibility of the colloids, and (c) the diffusion of colloids from the immobile intraaggregate water to the mobile convective water.
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Fig. 2. Examples of development of effluent outflow rates as a function of time after initiation of rainwater irrigation at 12 and 43% clay with initial matric potentials (IMP) of 2.5, 100, and 15500 hPa.
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Fig. 3. Average values of early tritium breakthrough, expressed as the number of pore volumes eluted when 12.5% of the applied tritium has been leached. Error bars: ±SE.
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Fig. 4. Effluent colloid concentration against number of eluted pore volumes (V/V0) as a function of clay content and initial matric potential (IMP). Replicate columns are represented by different symbols.
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Fig. 5. Measured total organic C (TOC, filled symbols) and estimated particulate organic C (POC, open symbols) against number of eluted pore volumes (V/V0) as a function of clay content and initial matric potential (IMP). Replicate columns are represented by different symbols.
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Fig. 6. Effect of clay content and initial matric potential (IMP) on (a) accumulated colloid mass leached after three pore volumes, (b) accumulated total organic C (TOC) leached after three pore volumes, and (c) amount of low-energy water-dispersible colloids (LE-WDC) from Kjaergaard et al. (2004a). Error bars: ±SE.
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Fig. 7. Plot of accumulated colloid mass (filled symbols) and electric conductivity (EC, open symbols) against square root of time for 12, 18, and 28% clay and initial matric potential (IMP) of 2.5, 100, and 15500 hPa. Dotted lines mark leaching of one pore volume. Replicates are represented by different symbols.
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Copyright © 2004 by the Soil Science Society of America.