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Coupled Processes of Fluid Flow, Solute Transport, and Geochemical Reactions in Reactive Barriers

^a Korea Institute of Water and Environment, Korea Water Resources Corporation, Daejon, Korea
^b Department of Geological Sciences, The Ohio State University, Columbus, OH 43210
^c Earth Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720
^d Department of Environmental Science and Engineering, Kwangju Institute of Science and Technology, Gwangju, Korea

View larger version (21K): [in a new window]   Fig. 1. Reaction zone (red) and total Fe concentrations (mg L–1) in pore water (contour lines) observed at 38 d (Shi, 2000).

View larger version (35K): [in a new window]   Fig. 2. Profiles using the Carman–Kozeny model at 38 d for (a) permeability, (b) Fe(OH)3(s), (c) Fe3+, (d) pH, and (e) Cl–.

View larger version (38K): [in a new window]   Fig. 3. Profiles using Eq. [1] at 38 d for (a) permeability, (b) Fe(OH)3(s), (c) Fe3+, (d) pH, and (e) Cl–.

View larger version (36K): [in a new window]   Fig. 4. Development of reaction zones.

View larger version (96K): [in a new window]   Fig. 5. Random fields for (a) calcite content and (b) permeability.

View larger version (43K): [in a new window]   Fig. 6. Profiles for (a) permeability, (b) Fe(OH)3(s), (c) Fe3+, (d) pH, and (e) Cl– in the chemically heterogeneous porous medium at 38 d.

View larger version (54K): [in a new window]   Fig. 7. Profiles for (a) permeability, (b) Fe(OH)3(s), (c) Fe3+, (d) pH, and (e) Cl– in the physically heterogeneous porous medium at 38 d.