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Modeling Biodegradation of Organic Contaminants under Multiphase Conditions with TMVOCBio

Alfredo Battistelli*

Aquater SpA (ENI Group), Via Miralbello 53, 61047 San Lorenzo in Campo (PU), Italy (now at Aquater Division, Snamprogetti SpA, ENI Group)


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Fig. 1. Phase combinations and phase transitions modeled by TMVOC. g, w, and n denote gas, aqueous, and NAPL, respectively.

 


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Fig. 2. Batch test simulation: biodegradation of two primary substrates by a single microbial population limited by O2. (TMVOCBio: symbols; spreadsheet calculations: lines).

 


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Fig. 3. TMVOCBio simulated concentration of toluene at column outlet compared with the experimental data (dots) and simulated results (circles) of MacQuarrie et al. (1990).

 


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Fig. 4. TMVOCBio simulated concentration of O2 at column outlet compared with the experimental data (dots) and simulated results (circles) of MacQuarrie et al. (1990).

 


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Fig. 5. Dover Air Force Base problem: TMVOCBio simulated (lines) and measured (symbols) concentrations of tetrachloroethene (PCE), trichloroethene (TCE), dichloroethene (DCE), vinyl chloride (VC), and benzene.

 


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Fig. 6. Dover Air Force Base problem: TMVOCBio simulated (lines) and measured (symbols) concentrations of DO and methane.

 


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Fig. 7. Dover Air Force Base problem: BIOMOC simulated results.

 





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