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Published online 8 March 2006
Published in Vadose Zone J 5:469-479 (2006)
DOI: 10.2136/vzj2005.0057
© 2006 Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
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Release of Polycyclic Aromatic Hydrocarbons, Dissolved Organic Carbon, and Suspended Matter from Disturbed NAPL-Contaminated Gravelly Soil Material

Kai Uwe Totsche*, Steffen Jann and Ingrid Kögel-Knabner

Lehrstuhl Bodenkunde, Technische Univ. München, D-85350 Freising, Germany

Figure 1
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Fig. 1. Sketch of the soil column set-up. A: Solution storage bottle. B: Peristaltic pump. C: Soil column. G: Fraction collector. Dotted arrows indicate the flow direction.

 

Figure 2
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Fig. 2. Results of the chloride breakthrough for the fast column, the slow column and its repetition. Symbols indicate measurements, line the fit. Results of the two-site/two-region (TSTR) model are not included.

 

Figure 3
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Fig. 3. Course of pH and the electrical conductivities (EC). Slow column: solid triangles; fast column: solid circles. Flow-interrupts are indicated by the vertical lines.

 

Figure 4
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Fig. 4. Dissolved organic carbon (DOC). Slow column: solid triangles; fast column: solid circles. Flow-interrupts are indicated by the vertical lines.

 

Figure 5
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Fig. 5. Turbidity expressed as Formazine Attenuation Units (FAU) and concentrations of colloids and particles >0.7 µm. Slow column: solid triangles; fast column: solid circles. Flow-interrupts are indicated by the vertical lines.

 

Figure 6
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Fig. 6. Concentrations of the sums of the 16 EPA PAH in the filtrate. Slow column: solid triangles; fast column: solid circles. Flow-interrupts are indicated by the vertical lines.

 

Figure 7
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Fig. 7. Mean aqueous equilibrium concentrations estimated according to Raoult's law and mean measured concentrations of the single PAH in the filtrate. Slow column: solid triangles; fast column: solid circles; Naphthalene (Nap), Acenaphthylene (Acy), Acenaphthene (Ace), Fluorene (Flr), Phenanthrene (Phe), Anthracene (Ant), Fluoranthene (FlA), Pyrene (Pyr), Benz[a]anthracene (BaA), Chrysene (Chr), Benzo[b]fluoranthene (BbFlA), Benzo[k]fluoranthene (BkFlA), Benzo[a]pyrene (BaP), Indeno[1,2,3-c,d]pyrene (IcdP), Dibenz[a,h]anthracene (DahA), Benzo[g,h,i]perylene (BghiP).

 

Figure 8
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Fig. 8. Concentrations of the sums of the 16 EPA polycyclic aromatic hydrocarbons (PAH) in the retentate. Slow column: solid triangles; fast column: solid circles. Flow-interrupts are indicated by the vertical lines.

 

Figure 9
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Fig. 9. Polycyclic aromatic hydrocarbon (PAH) patterns in the soil material (sieved to 2 mm), in the filtrate and in the retentate. Slow column filtrate: solid triangles; fast column filtrate: solid circles; slow column retentate: solid diamonds; fast column retentate: solid squares; soil material: crosses. Flow-interrupts are indicated by the vertical lines.

 





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