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Fig. 7. Measured 14C gas-phase breakthrough curves (symbols) and simulated responses (lines) at each sampling level. Simulated curves were calculated from an analytical solution to a conceptual model that considers reactive diffusive transport in the gas phase, but neglects aqueous transport. Average column water content was set to 28%; Kd = 0.45 mg L–1 was determined via least squares fit to the observations.





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